Large language model (LLM) agents have demonstrated remarkable capabilities in software engineering and cybersecurity tasks, including code generation, vulnerability discovery, and automated testing. One critical but underexplored application is automated web vulnerability reproduction, which transforms vulnerability reports into working exploits. Although recent advances suggest promising potential, challenges remain in applying LLM agents to real-world web vulnerability reproduction scenarios. In this paper, we present the first comprehensive evaluation of state-of-the-art LLM agents for automated web vulnerability reproduction. We systematically assess 20 agents from software engineering, cybersecurity, and general domains across 16 dimensions, including technical capabilities, environment adaptability, and user experience factors, on 3 representative web vulnerabilities. Based on the results, we select three top-performing agents (OpenHands, SWE-agent, and CAI) for in-depth evaluation on our benchmark dataset of 80 real-world CVEs spanning 7 vulnerability types and 6 web technologies. Our results reveal that while LLM agents achieve reasonable success on simple library-based vulnerabilities, they consistently fail on complex service-based vulnerabilities requiring multi-component environments. Complex environment configurations and authentication barriers create a gap where agents can execute exploit code but fail to trigger actual vulnerabilities. We observe high sensitivity to input guidance, with performance degrading by over 33% under incomplete authentication information. Our findings highlight the significant gap between current LLM agent capabilities and the demands of reliable automated vulnerability reproduction, emphasizing the need for advances in environmental adaptation and autonomous problem-solving capabilities.